English Information
業績Publication

業績

原著論文

  1. “Organophotocatalytic access to C-glycosides: multicomponent coupling reactions using glycosyl bromides”
    N. Sawada, Z. Yu, H. Takinami, D. Inoue, T. Ghosh, N. Sasaki, T. Nokami,* T. Taniguchi, M. Abe,* T. Koike
    Chem. Commun., 2024,60, 8684-8687.
  2. “One-Electron Injection-triggered Radical Reaction of Alkyl Benzoates Promoted by 1,4-Bis(diphenylamino)benzene Photocatalysis”
    T. Koike,* R. Okumura, T. Kato, M. Abe, M. Akita
    ChemCatChem, 2023,15, e202201311.
  3. “Assemblies of 1,4-Bis(diarylamino)naphthalenes and Aromatic Amphiphiles: Highly Reducing Photoredox Catalysis in Water”
    Y. Hyodo, K. Takahashi, Y. Chitose, M. Abe, M. Yoshizawa, T. Koike,* M. Akita*
    Synlett, 2022,33, 1184-1188.
  4. “Simple Generation of Various α-Monofluoroalkyl Radicals by Organic Photoredox Catalysis: Modular Synthesis of β-Monofluoroketones”
    R. Taniguchi, N. Noto, S. Tanaka, K. Takahashi, S. K. Sarkar, R. Oyama, M. Abe, T. Koike,* M. Akita*
    Chem. Commun., 2021,57, 2609-2672. Selected as “Front Inside Cover”
  5. “Chemistry of Tertiary Carbon Center in the Formation of Congested C−O Ether Bonds”
    G. Hirata, K. Takeuchi, Y. Shimoharai, M. Sumimoto, H. Kaizawa,T. Nokami,* T. Koike,* M. Abe,* E. Shirakawa,* T. Nishikata*
    Angew. Chem. Int. Ed., 2021, 60, 4329–4334. Selected as “Front Cover”
  6. “Transition Metal-Free Supramolecular Photoredox Catalysis in Water: A Phenoxazine Photocatalyst Encapsulated in V-Shaped Aromatic Amphiphiles”
    N. Noto, Y. Hyodo, M. Yoshizawa, T. Koike,* M. Akita*
    ACS Catal., 2020, 10, 14283-14289.
  7. “Laser Flash Photolysis Studies on Radical Monofluoromethylation by (Diarylamino)naphthalene Photoredox Catalysis: Long Lifetime of the Excited State is Not Always a Requisite”
    N. Noto, K. Takahashi, S. Goryo, A. Takakado, K. Iwata, T. Koike,* M. Akita*
    J. Org. Chem., 2020, 85, 13220-13227.
  8. “Energy transfer-driven regioselective synthesis of functionalized phenanthridines by visible-light Ir photocatalysis”
    Y. Matsushita, R. Ochi, Y. Tanaka, T. Koike,* M. Akita*
    Org. Chem. Front., 2020, 7, 1243–1248.
  9. “Fluoroalkanesulfinate Salts as Dual Fluoroalkyl and SO2 Sources: Atom-Economical Fluoroalkyl-Sulfonylation of Alkenes and Alkynes by Photoredox Catalysis”
    S. Tanaka, Y. Nakayama, Y. Konishi, T. Koike,* M. Akita*
    Org. Lett., 2020, 22, 2801–2805.
  10. “Keto-Difluoromethylation of Aromatic Alkenes by Photoredox Catalysis: Step-Economical Synthesis of α-CF2H-Substituted Ketones in Flow”
    Y. Nakayama, G. Ando, M. Abe, T. Koike,* M. Akita*
    ACS Catal., 2019, 9, 6555–6563. Highlighted in “Synfacts”
  11. “Visible Light-Triggered Monofluoromethylation of Alkenes by Strongly Reducing 1,4-Bis(diphenylamino)naphthalene Photoredox Catalysis”
    N. Naoki, T. Koike,* M. Akita*
    ACS Catal., 2019, 9, 4382–4387.
  12. “Strongly Reducing (Diarylamino)anthracene Catalyst for Metal-Free Visible-Light Photocatalytic Fluoroalkylation”
    N. Naoki, Y. Tanaka, T. Koike,* M. Akita*
    ACS Catal., 2018, 8, 9408–9419. Selected as “Front Cover”
  13. “Photoredox Radical C－H Oxygenation of Aromatics with Aroyloxylutidinium Salts”
    K. Miyazawa, R. Ochi, T. Koike,* M. Akita*
    Org. Chem. Front., 2018, 5, 1406–1410. Selected as “Front Cover”
  14. “Metal-Free Di- and Tri-Fluoromethylation of Alkenes Realized by Visible-Light-Induced Perylene Photoredox Catalysis”
    N. Naoki, T. Koike,* M. Akita*
    Chem. Sci., 2017, 8, 6375–6379.
  15. “Photoredox-Catalyzed Oxytrifluoromethylation of Allenes: Stereoselective Synthesis of 2-Trifluoromethylated Allyl Acetates”
    R. Tomita, T. Koike,* M. Akita*
    Chem. Commun., 2017, 53, 4681–4684. Selected as “Back Cover”
  16. “Photocatalytic Trifluoromethylthiolation of Aromatic Alkenes Associated with Hydroxylation and Alkoxylation”
    Y. Li, T. Koike,* M. Akita*
    Asian. J. Org. Chem., 2017, 6, 445–448. Selected as “Front Cover” and “Readers’ Choice 2019”
  17. “Diastereoselective Synthesis of CF3- and CF2H-Substituted Spiroethers from Aryl-Fused Cycloalkenylalkanols by Photoredox Catalysis”
    N. Naoki, T. Koike,* M. Akita*
    J. Org. Chem., 2016, 81, 7064–7071. Highlighted in “Org. Process. Res. Der. Vol. 21”
  18. “Aminohydroxylation of Olefins with Iminopyridinium Ylides by Dual Ir Photocatalysis and Sc(OTf)3 Catalysis”
    K. Miyazawa, T. Koike,* M. Akita*
    Tetrahedron, 2016, 72, 7813–7820.
  19. “Radical Pentafluorosulfanylphenylation of Styrenes by Photoredox Catalysis”
    Y. Li, T. Koike,* M. Akita*
    Synlett, 2016, 27, 736–740. Highlighted in “Synform News”
  20. “Oxydifluoromethylation of Alkenes by Photoredox Catalysis: Simple Synthesis of CF2H-Containing Alcohols”
    Y. Arai, R. Tomita, G. Ando, T. Koike,* M. Akita*
    Chem. Eur. J., 2016, 22, 1262–1265.
  21. “Trifluoromethylation of Aromatic Alkenes by Visible-Light-Driven Photoredox Catalysis: Direct Conversion of Alkenes to 3-Trifluoromethyl-1-propenyl and 1,3-Bis(trifluoromethyl)-1-propenyl Derivatives”
    M. Asano, R. Tomita, T. Koike,* M. Akita*
    J. Fluorine Chem., 2015,179, 83–88.
  22. “Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes”
    R. Tomita, T. Koike,* M. Akita*
    Angew. Chem. Int. Ed., 2015, 54, 12923–12927.
  23. “Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis”
    K. Miyazawa, T. Koike,* M. Akita*
    Chem. Eur. J., 2015, 21, 11677–11680.
  24. “Anti-Diastereoselective Synthesis of CF3-Containing Spirooxazolines and Spirooxazines via Regiospecific Trifluoromethylative Spirocyclization by Photoredox Catalysis”
    N. Noto, K. Miyazawa, T. Koike,* M. Akita*
    Org. Lett., 2015, 17, 3710–3713. Highlighted in “Synfacts” and “ACS Select Virtual Issue”
  25. “Alkyl- and Aryl-Thioalkylation of Olefins with Organotrifluoroborates by Photoredox Catalysis”
    Y. Li, K. Miyazawa, T. Koike,* M. Akita*
    Org. Chem. Front., 2015, 2, 319–323. Selected as “Inside Cover”
  26. “Redox-Economical Radical Generation from Organoborates and Carboxylic Acids by Organic Photoredox Catalysis”
    T. Chinzei, K. Miyazawa, Y. Yasu, T. Koike,* M. Akita*
    RSC Adv., 2015, 5, 21297–21300.
  27. “Synthesis and Properties of Diiron Complexes with Heteroaromatic Linkers: An Approach for Modulation of Organometallic Molecular Wire”
    Y. Tanaka, T. Ishisaka, T. Koike, M. Akita*
    Polyhedron, 2015, 86, 105–110.
  28. “Hydroaminomethylation of Olefins with Aminomethyltrifluoroborate by Photoredox Catalysis”
    K. Miyazawa, T. Koike,* M. Akita*
    Adv. Synth. Catal., 2014, 356, 2749–2755. Selected as “Cover”
  29. “Combining Photoredox-Catalyzed Trifluoromethylation and Oxidation with DMSO: Facile Synthesis of -Trifluoromethylated Ketones from Aromatic Alkenes”
    R. Tomita, Y. Yasu, T. Koike,* M. Akita*
    Angew. Chem. Int. Ed., 2014, 53, 7144–7148. Selected as “Inside Cover”
  30. “Direct C-H Trifluoromethylation of Di- and Trisubstituted Alkenes by Photoredox Catalysis”
    R. Tomita, Y. Yasu, T. Koike,* M. Akita*
    Beilstein J. Org. Chem., 2014, 10, 1099–1106.
  31. “Highly Regio- and Diastereoselective Synthesis of CF3-Substituted Lactones via Photoredox-Catalyzed Carbolactonization of Alkenoic Acids”
    Y. Yasu, Y. Arai, R. Tomita, T. Koike,* M. Akita*
    Org. Lett., 2014,16, 780–783.
  32. “Visible-Light-Induced Hydroalkoxymethylation of Electron-Deficient Alkenes by Photoredox Catalysis”
    K. Miyazawa, Y. Yasu, T. Koike,* M. Akita*
    Chem. Commun., 2013, 49, 7249–7251.
  33. “Intermolecular Aminotrifluoromethylation of Alkenes by Visible-Light-Driven Photoredox Catalysis”
    Y. Yasu, T. Koike,* M. Akita*
    Org. Lett., 2013, 15, 2136–2139. Highlighted in “Organic Chemistry Portal”
  34. “Visible-light-induced Synthesis of a Variety of Trifluoromethylated Alkenes from Potassium Vinyltrifluoroborates by Photoredox Catalysis”
    Y. Yasu, T. Koike,* M. Akita*
    Chem. Commun., 2013, 49, 2037–2039.
  35. “Visible-Light-induced Selective Generation of Radicals from Organoborates by Photoredox Catalysis”
    Y. Yasu, T. Koike,* M. Akita*
    Adv. Synth. Catal., 2012, 354, 3414–3420.
  36. “Visible-light-driven Oxidation of 1,3-Dicarbonyl Compounds via Catalytic Disproportionation of TEMPO by Photoredox Catalysis”
    T. Koike,* Y. Yasu, M. Akita*
    Chem. Lett., 2012, 41, 999–1001.
  37. “Three-component Oxytrifluoromethylation of Alkenes: Highly Efficient and Regioselective Difunctionalization of C=C Bonds Mediated by Photoredox Catalysts”
    Y. Yasu, T. Koike,* M. Akita*
    Angew. Chem. Int. Ed., 2012, 51, 9567–9571.
  38. “Theoretical Study on the Photocyclization Mechanism of Diarylethenes with Transition-Metal Substituents”
    M. Hatakeyama, S. Yokojima, K. Shinoda, T. Koike, M. Akita, S. Nakamura*
    Bull. Chem. Soc. Jpn., 2012, 85, 679-686.
  39. “Sunlight-driven Synthesis of ɤ-Diketones via Oxidative Coupling of Enamines with Silyl Enol Ethers Catalyzed by [Ru(bpy)3]2+”
    Y. Yasu, T. Koike,* M. Akita*
    Chem. Commun., 2012, 48, 5355–5357.
  40. “Color Change of Redox-active Organometallic Dithienylethene Complexes by Photochemical and Redox Processes”
    H. Li, T. Koike, M. Akita*
    Dyes and Pigments 2012, 92, 854–860.
  41. “Photo- and Electro-Chromic Organometallics with Dithienylethene (DTE) Linker, L2CpM-DTE-MCpL2: Dually Stimuli-Responsive Molecular Switch”
    K. Motoyama, H. Li, T. Koike, M. Hatakeyama, S. Yokojima, S. Nakamura, M. Akita*
    Dalton Trans., 2011, 40, 10643–10657.
  42. “Making Organometallic Molecular Wire via Oxidative Ligand Coupling”
    K. Johno, Y. Tanaka, T. Koike, M. Akita*
    Dalton Trans., 2011, 40, 8089–8091.
  43. “3,5-Bis(diphenylphosphinoethyl)pyrazolate Ligand (PNNPC2) and Its Dirhodium Complexes: Comparison with Related Quadridentate Dinucleating Diphenylphosphinomethyl (PNNPPy) and Phthalazine Derivatives (PNNPPh)”
    A. Gondoh, T. Koike, M. Akita*
    Inorg. Chim. Acta 2011, 374, 489–498.
  44. “Dirhodium Complexes Bridged by Bis(diphenylphosphino)phthalazine (PNNPPh): Central Ring Size and Charge Effects as Compared with the Pyrazolate Derivative (PNNPPy)”
    T. Yamaguchi, T. Koike, M. Akita*
    Organometallics 2010, 29, 6493–6502.
  45. “Reversible, Fine Performance Tuning of Organometallic Molecular Wire by Addition, Ligand Replacement and Removal of Dicobalt Fragments”
    Y. Tanaka, T. Koike, M. Akita*
    Eur. J. Inorg. Chem. 2010, 23, 3517–3575. Selected as “Highlight”
  46. “2-Dimensional Molecular Wiring Based on Toroidal Delocalization of Hexaarylbenzene”
    Y. Tanaka, T. Koike, M. Akita*
    Chem. Commun. 2010, 4529–4531.
  47. “Photochromic Organometallics with a Dithienylethene (DTE) Bridge, Y–C≡C-DTE–C≡C-Y (Y = {MCp*(dppe)}): Photoswitchable Molecular Wire (M = Fe) vs. Dual Photo- and Electro-chromism (M = Ru)”
    Y. Tanaka, T. Ishisaka, A. Inagaki, T. Koike, C. Lapinte, M. Akita*
    Chem. Eur. J. 2010, 16, 4762–4776. Selected as “Cover”
  48. “Photoinduced Oxyamination of Enamines and Aldehydes with TEMPO Catalyzed by [Ru(bpy)3]2+”
    T. Koike,* M. Akita*
    Chem. Lett. 2009, 38, 166–167.
  49. “Remarkable Switching Behavior of Bimodally Stimuli-responsive Photochromic Dithienylethenes with Redox-active Organometallic Attachments”
    K. Motoyama, T. Koike, M. Akita*
    Chem. Commun. 2008, 5812–5814.
  50. “Aerobic Oxidation of Alcohols with Bifunctional Transition Metal Catalysts Bearing C–N Chelate Ligands”
    S. Arita, T. Koike, Y. Kayaki, T. Ikariya*
    Chem. Asian. J. 2008, 3, 1479–1485.
  51. “Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C–N Chelate Ligands”
    S. Arita, T. Koike, Y. Kayaki, T. Ikariya*
    Organometallics 2008, 27, 2795–2802.
  52. “Aerobic Oxidative Kinetic Resolution of Racemic Secondary Alcohols with Chiral Bifunctional Amido Complexes”
    S. Arita, T. Koike, Y. Kayaki, T. Ikariya*
    Angew. Chem. Int. Ed. 2008, 47, 2447–2449. Selected as “VIP”
  53. “Synthesis and Properties of Alkylruthenium Complexes Bearing Primary and Secondary Amine Ligands”
    T. Koike, T. Ikariya*
    J. Organomet. Chem. 2007, 692, 408–419.
  54. “Reaction of 16-Electron Ruthenium and Iridium Amide Complexes with Acidic Alcohols: Intramolecular C-H Bond Activation and the Isolation of Cyclometalated Complexes”
    T. Koike, T. Ikariya*
    Organometallics, 2005, 24, 724–730.
  55. “Mechanistic Aspects of Formation of Chiral Ruthenium Hydride Complexes from 16-Electron Ruthenium Amide Complexes and Formic Acid: Facile Reversible Decarboxylation and Carboxylation”
    T. Koike, T. Ikariya*
    Adv. Synth. Catal., 2004, 346, 37–41.
  56. “Stereoselective Synthesis of Optically Active α-Hydroxy Ketones and anti-1,2-Diols via Asymmetric Transfer Hydrogenation of Unsymmetrically Substituted 1,2-Diketones”
    T. Koike, K. Murata, T. Ikariya*
    Org. Lett., 2000, 2, 3833–3836.

著書・総説・記事

  1. “Diastereoselectivity in Photoredox Catalysis”
    T. Koike*
    Comprehensive Chirality, 2nd edition; Cossy, J., Ed., Elsevier: Academic Press, 2024, 30-49.
  2. “Small Aromatics Bearing Two Diarylamino Termini: Highly Reducing Orgnic Photocatalysts”
    T. Koike*
    Synlett, 2024, 35, 412-418.
  3. “Recent progress in photocatalytic reactions involving the excitation of electron-primed catalysts”
    T. Koike*
    J. Photochem. Photobio., 2023, 17, 100205.
  4. “高還元力有機分子光レドックス触媒が拓くラジカル的フルオロアルキル化の新展開”
    小池隆司
    The Chemical Times　2023, 270, 21-26.
  5. “光触媒的一電子注入法が拓く合成化学”
    小池隆司
    光化学　2023, 54, 54-59.
  6. “Fluoroalkyl Sulfoximines for Versatile Photocatalytic Radical Fluoroalkylations”
    T. Koike*
    Chem. Rec., 2023, 23, e202300032. Selected as “Cover Feature”
  7. “太陽光・可視光エネルギーが駆動する光触媒的精密有機合成”
    小池隆司
    エネルギー・資源　特集「光エネルギーによる化学変換の最前線」、2023, 44, 46-50.
  8. “Chap 53 Synthesis of Organofluorine Compounds”
    T. Koike*
    Handbook of Inorganic Photochemistry; D.W. Bahnemann, A. O. T. Patrocinio, Eds., Springer, 2022, 1563–1578.
  9. “第3章 可視光フォトレドックス触媒によるトリフルオロメチル化反応”
    小池隆司、穐田宗隆
    CSJ Current Review 43 有機光反応の化学（日本化学会編）、化学同人、2022, 56-62.
  10. “第6章 金属錯体/有機光触媒を内包した水溶性カプセル触媒”
    吉沢道人、小池隆司
    水中有機合成の開発動向（監修：小林修、北之園拓）、シーエムシー出版、2022, 68-82.
  11. “Chap 8 Photochemical Paired Transformations”
    T. Koike,* M. Akita
    Organic Redox Chemistry; J.-i. Yoshida, F. W. Patureau, Eds., Wiley-VCH, 2021, 187–208.
  12. “Modern Synthetic Strategies for One-Electron Injection”
    T. Koike, M. Akita*
    Trends in Chemistry, 2021, 3, 416–427.
  13. “Chap 7 Photoredox Catalysis in Fluorination and Trifluoromethylation”
    T. Koike,* M. Akita*
    Organofluorine Chemistry: Synthesis, Modeling, and Applications; K. J. Szabó, N. Selander, Eds., Wiley-VCH, 2021, 225–240.
  14. “Frontiers in Radical Fluoromethylation by Visible-Light Organic Photocatalysis”
    T. Koike*
    Asian J. Org. Chem., 2020, 9, 529–537.
  15. “Recent Progress in Photochemical Radical Di- and Mono-Fluoromethylation”
    T. Koike,* M. Akita*
    Org. Biomol. Chem., 2019, 17, 5413–5419.
  16. “可視光レドックス触媒作用：ラジカル反応の新戦略”
    小池隆司*
    有機合成化学協会誌、2019、77、414−423.
  17. “Chap 18 Photocatalytic Introduction of Fluorinated Groups”
    T. Koike,* M. Akita*
    Science of Synthesis: Photocatalysis in Organic Synthesis; B. König, Ed., Thieme, 2019, 559–574.
  18. “New Horizons of Photocatalytic Fluoromethylative Difunctionalization of Alkenes”
    T. Koike,* M. Akita*
    Chem, 2018, 4, 409–437.
  19. “Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon－Carbon Multiple Bonds”
    T. Koike,* M. Akita*
    Acc. Chem. Res., 2016, 49, 1937–1945.
  20. “Combination of Organotrifluoroborates with Photoredox Catalysis Marking a New Phase in Organic Radical Chemistry”
    T. Koike,* M. Akita*
    Org. Biomol. Chem., 2016, 14, 6886–6890. Selected as “Inside Cover” and “Hot Articles”
  21. “A Versatile Strategy for Difunctionalization of Carbon–Carbon Multiple Bonds by Photoredox Catalysis”
    T. Koike,* M. Akita*
    Org. Chem. Front., 2016, 3, 1345–1349.
  22. “Sunlight-Driven Trifluoromethylation of Olefinic Substrates by Photoredox Catalysis: A Green Organic Process”
    M. Akita,* T. Koike
    Compt. Rend. Chim., 2015, 18, 742–751.
  23. “可視光（太陽光）促進有機金属反応：フォトレドックス触媒と機能分担型二核錯体触媒系”
    穐田宗隆、* 小池隆司、稲垣昭子
    有機合成化学協会誌、2014、72、538−547.
  24. “Visible-Light-Induced Redox Reactions by Ruthenium Photoredox Catalyst”
    T. Koike,* M. Akita*
    Top. Organomet. Chem., 2014, 48, 371–396.
  25. “Recent Progress in Transition-metal-catalyzed Trifluoromethylation of Olefins Using Electrophilic CF3 Reagents”
    T. Koike,* M. Akita*
    J. Fluorine Chem., 2014, 167, 30–36.
  26. “Visible-Light Radical Reaction Designed by Ru- and Ir-based Photoredox Catalysis”
    T. Koike,* M. Akita*
    Inorg. Chem. Front., 2014, 1, 562–576. Selected as “Cover”
  27. “Trifluoromethylation by Visible-Light-Driven Photoredox Catalysis”
    T. Koike,* M. Akita*
    Top. Catal., 2014, 57, 967–974.
  28. “ 高原子価有機銅(III)種によるアリール化反応（Review de Debut）”
    小池隆司
    有機合成化学協会誌、2014、72、431−432.
  29. “Chapter 11 Photochromic Organometallics: Redox-Active Iron and Ruthenium Complexes with Photochromic DTE Ligand”
    T. Koike, M. Akita
    New Frontiers in Photochromism; M. Irie, Y. Yokoyama and T. Seki, Eds., Springer Japan, 2013, 205-224.
  30. “第一章6節フォトクロミックオルガノメタリックス”
    小池隆司、穐田宗隆
    フォトクロミズムの新展開と光メカニカル機能材料（監修：入江正浩、関隆広）、シーエムシー出版、2011, 47-53.
  31. “Visible-Light-Induced Photoredox Catalysis: An Easy Access to Green Radical Chemistry”
    T. Koike,* M. Akita*
    Synlett, 2013, 24, 2492–2505.
  32. “Chemistry of Polycarbon Species: From Clusters to Molecular Devices”
    M. Akita,* T. Koike
    Dalton Trans. 2008, 27, 3523–3530. Invited Perspective selected as “Cover”

特許

  1. “高い還元力を有する芳香環光レドックス触媒”
    小池隆司、納戸直木、谷口諒、髙橋慶悟、穐田宗隆
    特願2019-160380，2019年9月3日,特許第7341464号, 2023 年9月1日（出願人　東京工業大学）
  2. “多環芳香族炭化水素を光触媒とするフルオロメチル基含有化合物の製造方法”
    小池隆司、納戸直木、穐田宗隆
    特願2017-0028880，2017年2月20日（出願人　旭硝子株式会社・東京工業大学）
  3. “ジフルオロメチル基含有アルコールの製造法”
    小池隆司、新井悠亮、穐田宗隆
    特願2015−045831，2015年3月9日，特開2016-166137, 2016年9月15日, 特許第6462426号, 2019 年1 月11日（出願人　東ソー・エフテック株式会社・東京工業大学）
  4. “1，2−アミノアルコール骨格を持つ化合物の製造法”
    小池隆司、宮澤和己、穐田宗隆
    特願2014-241563，2014年11月28日，特開2016-102090，2016年6月2日（出願人　東京工業大学）
  5. “トリフルオロメチル基含有オキサジン類及びその製造法”
    小池隆司、新井悠亮、安祐輔、穐田宗隆
    特願2014-036832, 2014年2月27日，特開2015-160828, 2015年9月7日, 特許第6378894号, 2018 年8 月3日（出願人　東ソー・エフテック株式会社・東京工業大学）
  6. “トリフルオロメチル基含有アミノ化合物の製造法”
    小池隆司、安祐輔、穐田宗隆
    特願2013-029911, 2013年2月19日, 特開2014-159382, 2014年9月4日, 特許第6014512号, 2016 年9 月30日（出願人　東ソー・エフテック株式会社・東京工業大学）

招待講演

  1. 5th Workshop on Radical and Electron Transfer Reactions in Regensburg Univ.(RETR-5R)（Regensburg Univ.），9月7日，2024年
    “New Strategies for Generation of Fluorinated Alkyl Radicals Using Highly Reducing Organic Photoredox Catalysts”
  2. 3rd Workshop on Radical and Electron Transfer Reactions (RETR-3)（Kwansei Gakuin Univ.），9月4日，2023年
    “Photocatalytic Radical Alkylation Using Alkyl Benzoates”
  3. 10th Pacific Symposium on Radical Chemistry (PSRC)（Kyoto University），6月5日，2023年
    “Radical Fluoroalkylation Reactions by Highly Reducing Organic Photocatalysts”
  4. 日本化学会　第103春季年会コラボレーション企画「CREST革新的反応　成果報告会」（東京理科大学　野田キャンパス），3月24日，2023年
    “光触媒的一電子注入法による難還元性物質の変換”
  5. 11th Singapore International Chemistry Conference (SICC-11)（Innovis Building, Singapore），12月13日，2022年
    “Radical Fluoroalkylation Reactions by Means of Organic Photocatalysis”
  6. Workshop on Radical and Electron Transfer Reactions (RETR)（関西学院大学），9月23日，2022年
    “Strategies for Electron Transfer by Means of Organic Photocatalysis: Beyond Metallic Reagents”
  7. 2022年光化学討論会特別シンポジウム「躍進する光有機化学」（京都大学），9月15日，2022年
    “光触媒的一電子注入法が拓く合成化学”
  8. 第２回酸化反応化学セミナー（同志社大学），8月5日，2022年
    “光触媒的一電子注入法が拓く新合成戦略”
  9. 京都大学エネルギー理工学研究所講演会（京都大学宇治キャンパス），8月4日，2022年
    “可視光レドックス触媒反応：光と電子を試薬とする触媒反応”
  10. 有機合成2月セミナー「有機合成のニュートレンド2022」（オンライン），2月3日，2022年
    “光触媒的一電子注入法が拓く分子変換技術”
  11. 第141回フロンティア材料研究所学術講演会「細孔･錯体･界面での分子活性化･触媒作用」（オンライン），12月6日，2021年
    “光レドックス触媒作用：一電子還元合成化学の進展”
  12. 第127回触媒討論会特別シンポジウム（オンライン），3月17日，2021年
    “可視光レドックス触媒作用が拓くラジカル的分子変換法”
  13. 第126回触媒討論会特別シンポジウム（オンライン），9月16日，2020年
    “可視光触媒作用が拓く新合成戦略”
  14. The 1st F-Materials International Symposium（群馬大学），2月14日，2020年
    “Design of Visible-Light Photoredox Systems for Radical Fluoroalkylation”
  15. The 4th International Symposium on Precisely Designed Catalysts with Customized Scaffolding（東大寺ミュージアム），12月5日，2019年
    “New Design of Highly Reducing Organic Photoredox Catalysts”
  16. 第4回有機若手ワークショップ（京都大学），11月14日，2019年
    “高い還元力を有する芳香環光レドックス触媒系の開発とラジカル的フルオロアルキル化反応”
  17. 2019年光化学討論会（名古屋大学），9月10日，2019年
    “Design of Visible-Light Photoredox Systems for Metal-free Radical Fluoroalkylation”
  18. 第69回錯体化学討論会（名古屋大学），9月21日，2019年
    “Visible-Light Photoredox Catalysis: New Strategies for Radical Reactions”
  19. 2019 Gordon Research Conference: Light-Driven Reactions, Materials and Devices (Stonehill College, MA, USA), July 14th–19th, 2019
    “Design of Photoredox Systems for Metal-Free Radical Fluoroalkylation”
  20. 9th Pacific Symposium on Radical Chemistry (Monterey, CA, USA), June 16th–21st, 2019
    “Photoredox-Catalyzed Reactions of N-Aminopyridinium Derivatives”
  21. パイスター分子制御による未来型物質変換研究拠点公開シンポジウム（関西学院大学），12月15日，2018年
    “芳香環フォトレドックス触媒系の開拓”
  22. 第35回有機合成化学セミナー（山形天童　滝の湯），9月18~20日，2018年
    “可視光フォトレドックス触媒作用を基盤としたラジカル的官能基化法の開発”
  23. 第8回フッ素化学若手の会（袋田温泉），8月20~21日，2018年
    “炭素―炭素不飽和結合の光触媒的フルオロアルキル化反応”
  24. 1st Sino-Japanese Symposium on Catalysis for Precision Synthesis (Shanghai, China), May 27th–30th, 2018
    “Design of Photoredox Systems for Catalytic Fluoromethylation of Alkenes”
  25. 233rd ECS Meeting (Seattle, WA, USA), May 13nd–17th, 2018
    “Design of Photoredox Systems for Catalytic Fluoroalkylation of Alkenes”
  26. 東レ株式会社セミナー（医薬研究所），4月24日，2018年
    “フォトレドックス触媒作用の基礎と応用：フルオロメチル化を中心に”
  27. 日本化学会　第98春季年会特別企画「超スマート社会の実現に貢献するサステイナブル・機能レドックス化学」（日本大学　理工学部船橋キャンパス），3月20日，2018年
    “フォトレドックス触媒が拓く可視光駆動ラジカル官能基化”
  28. 塩野義製薬株式会社セミナー（杭瀬事業所），3月8日，2018年
    “フォトレドックス触媒が拓くフルオロメチル化”
  29. 中外製薬株式会社セミナー（鎌倉研究所），7月5日，2017年
    “フォトレドックス触媒が拓くフルオロアルキル化”
  30. 日本化学会　第97春季年会アジア国際シンポジウム (慶應義塾大学)，3月17日，2017年
    “Fine Design of Photoredox Systems for Catalytic Fluoromethylation”
  31. 高砂香料株式会社セミナー (平塚研究所)，3月8日，2017年
    “フォトレドックス触媒が拓く新合成戦略”
  32. 平成28年度日本化学会青森地区講演会 (弘前大学)，10月14日，2016年
    “フォトレドックス触媒反応：電子と光を試薬とする触媒反応”
  33. 2016 Pacific Rim Meeting on Electrochemical and Solid-State Science (PRiME 2016) (Honolulu, HI, USA), October 2nd-7th, 2016
    “Photoredox Catalysis: An Easy Access to Versatile Radical Functionalization”
  34. 旭硝子株式会社セミナー (横浜研究所)，2月10日，2016年
    “フォトレドックス触媒が拓くトリフルオロメチル化及びジフルオロメチル化反応”
  35. 2015 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2015)　(Hawaii), December 15th-20th, 2016
    “Regioselective Difunctionalization of Olefins by Photoredox Catalysis”
  36. 第3回アライアンス若手研究交流会　（九州大学先導化学研究所），11月16日, 2015年
    “フォトレドックス触媒による不飽和炭素結合のフルオロアルキル化”
  37. 日本化学会　第９５春季年会　若い世代の特別講演会（日本大学　理工学部船橋キャンパス），3月27日，2015年
    “フォトレドックス触媒が拓くオレフィンのラジカル的官能基化反応”
  38. 22nd Biennial Winter Fluorine Conference (TradeWinds Island Grand Resort, St. Pete Beach, FL), January 11th-26th, 2015
    “Trifluoromethylation of Olefins with Concomitant Functionalization by Photoredox Catalysis”
  39. 第１１回フッ素相模セミナー　（相模中央化学研究所），6月6日，2014年
    “フォトレドックス触媒反応：アルケン類のトリフルオロメチル二官能基化”

その他

  1. 東京化成工業株式会社から試薬製品化

    「光触媒的ジフルオロメチル化が可能なスルホニウム塩」
    (Difluoromethyl)bis(2,5-dimethylphenyl)sulfonium tetrafluoroborate (D5630)